Metal-halide perovskite semiconductors can compete with silicon counterparts for solar cells, LEDs: Road map for organic-inorganic hybrid perovskite semiconductors and devices

Local weather change and its penalties have gotten more and more apparent, and photo voltaic cells that convert the solar’s vitality into electrical energy will play a key function on this planet’s future vitality provide.

Widespread semiconductor supplies for photo voltaic cells, similar to silicon, have to be grown by way of an costly course of to keep away from defects inside their crystal construction that have an effect on performance. However metal-halide perovskite semiconductors are rising as a less expensive, various materials class, with wonderful and tunable performance in addition to straightforward processability.

In APL Supplies, from AIP Publishing, researchers current a highway map for organic-inorganic hybrid perovskite semiconductors and gadgets.

Perovskite semiconductors may be processed from resolution, and a semiconductor ink may be coated or just painted over surfaces to type the specified movie. This may be included into semiconductor gadgets, similar to photo voltaic cells or light-emitting diodes.

“For a few years, solution-processed semiconductors had been seen as unable to ship the identical performance as specifically grown crystalline semiconductors,” mentioned Lukas Schmidt-Mende, a co-author from the College of Konstanz in Germany. “The rationale behind this pondering was that easy resolution processing will inherently result in a relative excessive variety of defects throughout the fashioned crystal construction, which might negatively have an effect on its performance.”

It seems organic-inorganic hybrid perovskites are very defect-tolerant. Defects fashioned after processing don’t dramatically affect system performance, and for the primary time, hybrid perovskites are enabling environment friendly solution-processed gadgets.


“We will merely change the chemical composition of the perovskite to tune its bandgap, which permits us to alter the absorption profile,” mentioned Schmidt-Mende. “This can be utilized to arrange light-emitting diodes at completely different wavelengths or to tune the perovskite materials for tandem photo voltaic cells to optimize the absorption profile.”

Excessive defect tolerance, nonetheless, “got here as a shock that must be higher understood,” he mentioned. “Understanding the small print will assist to additional optimize the fabric, maybe to search out different related environment friendly options and provides us the prospect to enhance purposes based mostly on perovskite semiconductors.”

The group factors out that perovskite gadgets at the moment have two main drawbacks.

First, probably the most environment friendly gadgets all comprise poisonous lead and efforts to interchange it with much less poisonous components have to date been solely partly profitable. Second, perovskite gadgets have a decreased life span in comparison with silicon gadgets.

“Though the steadiness of perovskite gadgets has elevated dramatically through the previous few years, we nonetheless don’t perceive and haven’t overcome all of its degradation mechanisms,” mentioned Schmidt-Mende.

Many researchers are engaged on photo voltaic cells and, with the potential of tuning the bandgap, perovskites are intriguing for tandem purposes the place they could be mixed with a longtime silicon photo voltaic cell.

“Different purposes are light-emitting diodes, the place the colour of the sunshine emitted may be tuned by adjusting the chemical composition of the perovskite,” Schmidt-Mende mentioned. “As for different semiconductors, the listing of potential purposes is lengthy, and we’re simply starting to know this materials and its potential.”